The tropopause inversion layer in models and analyses

Recent high-resolution radiosonde climatologies have revealed a tropopause inversion layer (TIL) in the extratropics: temperature strongly increases just above a sharp local cold point tropopause. Here, it is asked to what extent a TIL exists in current general circulation models (GCMs) and meteorological analyses. Only a weak hint of a TIL exists in NCEP/NCAR reanalysis data. In contrast, the Canadian Middle Atmosphere Model (CMAM), a comprehensive GCM, exhibits a TIL of realistic strength. However, in data assimilation mode CMAM exhibits a much weaker TIL, especially in the Southern Hemisphere where only coarse satellite data are available. The discrepancy between the analyses and the GCM is thus hypothesized to be mainly due to data assimilation acting to smooth the observed strong curvature in temperature around the tropopause. This is confirmed in the reanalysis where the stratification around the tropopause exhibits a strong discontinuity at the start of the satellite era

Seismic interpretation and generation of key depth structure surfaces within the Devonian and Carboniferous of the Central North Sea, Quadrants 25 – 44 area

This report details the rationale, methodology and results of a regional seismic interpretation of the western margin of the Central North Sea (CNS) area, specifically over the Mid North Sea High area, the offshore extension of the Northumberland Trough and the Forth Approaches area. The aim of the interpretation was to create maps that show the distribution of Palaeozoic basins and highs, and where possible interpret key Devono-Carboniferous surfaces and main structural elements in order to build a tectono-stratigraphic model of the Palaeozoic geology. Some 50,000 line kilometres of predominantly 2D seismic data have been interpreted and tied to key released wells in the study area. The seismic and well data were augmented by donated reports from sponsor companies. A set of 5 depth structure maps of selected Palaeozoic horizons has been produced for the pre-Permian succession. These maps provide a key element to aid assessment of the petroleum prospectivity of the Palaeozoic within the study area. The surfaces, with a grid spacing of 5000 m, give a regional view of the topography of the horizons, and comprise: Upper Permian Base Zechstein Group; Lower Carboniferous near Top Scremerston Formation; Lower Carboniferous near Top Fell Sandstone Formation; Lower Carboniferous near Top Cementstone Formation; and Middle Devonian near Top Kyle Limestone Group. The regional structure map of the area constructed for this report and observations made from the seismic data, have been integrated with peer reviewed published information to describe a tectonostratigraphic model for the region (Leslie et. al., 2015). A new pre-Permian subcrop map is presented here that builds on existing publications (Smith,1985a, b; Kombrink et al., 2010) and incorporates all relevant new well penetrations since the previous map was published. The well dataset has been either validated or re-interpreted before being integrated with the new seismic interpretation (Kearsey et al., 2015). Figure 10 in Section 3.3.1 below summarises the regional structures referred to in the general observations listed below. General observations on the structures defined across Quadrants 29, 30, 31, 37, 38 and 39: The Middle-Upper Devonian basins and highs follow a NW-SE trend across Quadrants 29-30 and 37-38; Lower Carboniferous sequences (Tournaisian and Visean) are interpreted to be present in depocentres across much of the area covered by Quadrants 29 to 38; wells, mainly drilled on the structural highs, constrain the edge of the Lower Carboniferous basins; There is a structurally complicated area in the southernmost part of Quadrant 38 which comprises a folded Visean and probably Namurian succession. The structure can be interpreted either as an anticlinal rollover on a low-angle fault, or as a compressional anticlinal fold (see Figure 17 below). The structure trends broadly NNE-SSW, plunging northwards into Quadrant 38

Approximate ab initio calculation of vibrational properties of hydrogenated amorphous silicon with inner voids

We have performed an approximate ab initio calculation of vibrational properties of hydrogenated amorphous silicon (a-Si:H) using a molecular dynamics method. A 216 atom model for pure amorphous silicon (a-Si) has been employed as a starting point for our a-Si:H models with voids that were made by removing a cluster of silicon atoms out of the bulk and terminating the resulting dangling bonds with hydrogens. Our calculation shows that the presence of voids leads to localized low energy (30-50 cm^{-1}) states in the vibrational spectrum of the system. The nature and localization properties of these states are analyzed by various visualization techniques.Comment: 15 pages with 6 PS figures, to appear in PRB in December 199

A new multi-center approach to the exchange-correlation interactions in ab initio tight-binding methods

A new approximate method to calculate exchange-correlation contributions in the framework of first-principles tight-binding molecular dynamics methods has been developed. In the proposed scheme on-site (off-site) exchange-correlation matrix elements are expressed as a one-center (two-center) term plus a {\it correction} due to the rest of the atoms. The one-center (two-center) term is evaluated directly, while the {\it correction} is calculated using a variation of the Sankey-Niklewski \cite{Sankey89} approach generalized for arbitrary atomic-like basis sets. The proposed scheme for exchange-correlation part permits the accurate and computationally efficient calculation of corresponding tight-binding matrices and atomic forces for complex systems. We calculate bulk properties of selected transition (W,Pd), noble (Au) or simple (Al) metals, a semiconductor (Si) and the transition metal oxide Ti$O_2$ with the new method to demonstrate its flexibility and good accuracy.Comment: 17 pages, 5 figure

Climate, wildfire, and erosion ensemble foretells more sediment in western USA watersheds

The area burned annually by wildfires is expected to increase worldwide due to climate change. Burned areas increase soil erosion rates within watersheds, which can increase sedimentation in downstream rivers and reservoirs. However, which watersheds will be impacted by future wildfires is largely unknown. Using an ensemble of climate, fire, and erosion models, we show that postfire sedimentation is projected to increase for nearly nine tenths of watersheds by \u3e10% and for more than one third of watersheds by \u3e100% by the 2041 to 2050 decade in the western USA. The projected increases are statistically significant for more than eight tenths of the watersheds. In the western USA, many human communities rely on water from rivers and reservoirs that originates in watersheds where sedimentation is projected to increase. Increased sedimentation could negatively impact water supply and quality for some communities, in addition to affecting stream channel stability and aquatic ecosystems